http://www.threedollarsquirrel.com/kiln-mold/
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How long do you mold before you kiln it?
As soon as your piece is leather-hard and can be taken out of the mold or form without it slumping, then you can release it. That can depend on the type of mold or form you are using. A plaster mold or bisqued form will aid in drying your piece faster. A metal, fired ceramic, or plastic form which is not porous will slow down the drying time to get to a leather-hard consistency.
Next, you want to let your work dry thoroughly. That can take several days, depending on humidity in the studio and how thick it is. Check by putting it up against your cheek to feel if it is damp. If it feels cold and damp, then you want to let it dry some more. Hopefully your piece has walls that are even though out.
When dry you can fire it in a kiln at the appropriate firing schedule depending on thickness. The thicker it is, the more of a preheat and possibly slower firing you will want. Check my website for information such as "Guidelines for Clay Projects" and "5 Kiln Firing Schedules." Good luck.
How to Use Kiln Wash